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Being able to effectively tune the electron-transport properties of a single-molecule has been a long-standing issue towards the crystallization of molecular electronics, where individual molecules mimic the behavior of common electronic components as a true alternative to conventional silicon devices. To functionalize electron transport properties, each and every individual molecule must be precisely aligned in place with sub-nanometer precision. In that sense, stacks of self-assembled aromatic components in which non-covalently bound π-stacks act as replaceable modular components are promising building blocks.
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